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An older version of Cirno on pixiv known as Cirno-nee [チル姉] usually depicted wearing a yellow or orange scarf and a more mature demeanor, and sometimes has red-blue heterochromia. This version of Cirno appears on good terms with Remilia Scarlet and the other residents of the mansion.

(taken from Cirno Wiki)

Ricia(リーチャ) popularized the use of Cirno-nee with his Video manga series on NicoNico Douga.

As far as Ricia's Doujin goes, Cirno-nee is on really close terms with Remilia Scarlet as well as the rest of the Scarlet Mansion. Remilia and the Scarlet Mansion is also on friendly terms with the Makai residents such as Shinki and Yumeko. Sakuya deeply looks up to Cirno-nee as a sort of big sister character. While Sakuya-chan is still a child, everyone pretty much dotes on her causing her to be a little spoiled.

Other than wearing her traditional canon clothes along with just a yellow Scarf, Cirno-nee is also sometimes wearing a ⑨ hoodie and wearing her hair in an up pony-tail.

This tag implicates cirno (learn more).

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2girls :d >:) alternate_breast_size alternate_hair_length alternate_hairstyle blue_dress blue_eyes blue_hair bow breast_rest breasts breasts_on_head cirno cirno-nee commentary_request crossed_arms dress dual_persona eyebrows_visible_through_hair hair_between_eyes hair_bow hands_on_hips highres ice ice_wings large_breasts long_hair looking_at_viewer multiple_girls older open_mouth osashin_(osada) puffy_short_sleeves puffy_sleeves ribbon short_hair short_sleeves smile touhou v-shaped_eyebrows very_long_hair wings
1girl alternate_hairstyle blue_dress blue_eyes blue_hair boots cirno cirno-nee commentary_request dress hair_ribbon ice ice_wings looking_at_viewer ponytail ribbon scarf short_hair smile soiru solo touhou white_background wings
2girls ;) absurdres arm_at_side bad_proportions bikini bikini_tan blue_bikini blue_eyes blue_hair bow breasts child cirno cirno-nee cleavage cropped_legs dual_persona flat_chest flower food hair_bow half_updo highres ice ice_wings large_breasts long_hair mouth_hold multiple_girls navel older one-piece_tan one_eye_closed plant popsicle pushun_(muteki) short_hair sketch smile sunflower swimsuit tan tanline tanned_cirno touhou vines wings
1girl blue_dress blue_eyes blue_hair bow cirno cirno-nee dress hair_bow ice ice_wings konosuke_dagame long_hair long_sleeves looking_at_viewer scarf simple_background smile solo touhou wings